The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Organics (carbonyls) / Ketones,ketenes / CD3C(O)CD3 / Gierczak(2003)_232-295K_184.9nm

DATAFILE: CD3C(O)CD3_Gierczak(2003)_232-295K_184.9nm.txt
NAME: dimethyl-d6 ketone, acetone-d6
FORMULA: CD3C(O)CD3
AUTHOR(YEAR): Gierczak(2003)
T: 232-295K
λ: 184.9nm
BIBLIOGRAPHY: T. Gierczak, M.K. Gilles, S. Bauerle, and A.R. Ravishankara, "Reaction of hydroxyl radical with acetone. 1. Kinetics of the reactions of OH, OD, and 18OH with acetone and acetone-d6", J. Phys. Chem. A 107, 5014-5020 (2003); DOI: 10.1021/jp027301a
COMMENTS: The temperature dependence of absorption cross section at 184.9-nm (Hg pen-ray lamp) was fitted to an equation of the form

σ(T) = a + b × (1000/T) to yield

σ(T) = [(1.55 ± 0.35) + (0.698 ± 0.10) × (1000/T)]×10-18 cm2 molecule-1

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